Methane pyrolysis over porous particles
نویسندگان
چکیده
The deposition of carbon from methane pyrolysis on various porous media was investigated at 950–1100 ◦C. 7 Types unfunctionalized carriers were used, with pore sizes varying between 4 nm and 250 µm. Carbon over time measured in a single particle reactor. It found that the samples can exhibit both an induction period as well gradual stop deposition. An observed for α-Al2O3 samples, but not γ-Al2O3, SiC C carriers. Hence, slow start may be caused by substrate material. Furthermore, all apparent maximum loading observed. confirmed this is blockage, significant surface area remains these point loading. In fact, it fraction volume filled loading, function initial diameter. smaller pores fill to lesser extent than bigger pores. This achievable incorporated model. Using only parameter, could described.
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ژورنال
عنوان ژورنال: Catalysis Today
سال: 2023
ISSN: ['0920-5861', '1873-4308']
DOI: https://doi.org/10.1016/j.cattod.2023.114058